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Shanghai Jiao Tong University’s Liu Feng: AM = 17.6% at 18.4 cm²! Organic solar cells fabricated using low-toxicity solvents!

Organic photovoltaic devices (OPVs) aim to harness solar energy in an environmentally friendly, highly efficient, and low-cost manner, thereby offering a sustainable solution for both energy production and ecological conservation. In light of this, researchers led by Feng Liu at Shanghai Jiao Tong University have focused on optimizing the engineering fabrication techniques for organic photovoltaic devices and their mini-modules by developing solvent-processing methods with minimal ecological impact. A newly devised solvent-engineering strategy employs the environmentally benign o-xylene (OXY) together with a synergistic dual-additive system (DIM and DIB), achieving a record-breaking power conversion efficiency (PCE) of 20.0%—with a short-circuit current density (JSC) of 26.6 mA cm⁻², open-circuit voltage (VOC) of 0.935 V, and fill factor (FF) of 80.3%—while also demonstrating outstanding stability, retaining 82% of its initial performance after 1,500 hours. Mini-modules treated with the optimized TCE:OXY solvent blend (volume ratio 1:3) exhibit scalable performance, reaching an efficiency of 17.6% over an active area of 18.4 cm², which represents the highest efficiency achieved to date in the development of organic photovoltaic devices based on safe solvents. This work was recently published in the journal Advanced Materials under the title “Lowering toxicity of solvent in organic solar cells manufacturing for 20% efficiency.”

2025

05-02

Nankai University’s Yongsheng Liu in Angewandte Chemie: 20.82%! A D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–......Nankai University’s Yongsheng Liu in Angewandte Chemie: 20.82%! A D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A–D–A......

Two-dimensional (2D) Ruddlesden–Popper (RP) perovskites have emerged as promising photovoltaic materials. However, the large dielectric mismatch and high exciton binding energy arising from insulating spacer layers have hindered further improvements in their power conversion efficiency. In light of this, Yongsheng Liu and colleagues at Nankai University have developed two semiconductor spacers—MeBThMA and CNBThMA—for 2D RP perovskite solar cells. Compared with MeBThMA, the CNBThMA spacer, which features a donor–acceptor (D–A) architecture, exhibits a larger dipole moment and adopts a face-to-face molecular stacking arrangement in single crystals. This unique D–A structure effectively mitigates the dielectric mismatch between the organic and inorganic layers, facilitates favorable band alignment, tunes anisotropic charge transport properties, and enhances the film quality of layered RP perovskites. As a result, devices based on CNBThMA (with a nominal n value of 5) achieve a record-breaking power conversion efficiency of 20.82%, to the best of our knowledge the highest reported for a 2D RP perovskite solar cell employing a semiconductor spacer. Our work pioneers a novel approach to designing organic semiconductor spacers with a D–A architecture for high-efficiency 2D perovskite solar cells. The paper was recently published in Angewandte Chemie International Edition under the title “Semiconductor Spacers with Donor-Acceptor Structure Drive 2D Ruddlesden-Popper Perovskite Solar Cells Beyond 20% Efficiency.”

2025

03-26